The electron deficiency in the remaining carbon adjacent to the OS O 2 CH 3 group in adduct III facilitates nonenzymatic intramolecular nucleophilic attack at this carbon by a pair of electrons on the sulfur of the thioether, generating the glutathione S conjugate V and eliminating a second equivalent of methanesulfonate
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If the PSA is above the median, the risk of being diagnosed with prostate cancer is higher than in the general population